Abstract
The gaseous MgD2 molecule has been synthesized for the first time in an electrical discharge inside a high-temperature furnace. The high-resolution infrared emission spectrum of MgD2 was recorded with a Fourier transform spectrometer, and the antisymmetric stretching mode (v3) was detected near 1176.5 cm1. The v3 band was rotationally analyzed, and the r0 MgD bond distance was determined to be 1.700 874(8) Å.Key words: gaseous MgD2, vibration-rotation emission spectrum, Mg-D bond distance.
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