The Anomeric Effect and Associated Stereoelectronic Effects

Abstract

Anomeric effect - how it came to be postulated, John T. Edward anomeric and associated stereoeleconic effects - scope and controversy, Gregory R.J. Thatcher intramolecular strategies and stereoelectronic effects - glycosides and orthoesters hydrolysis revisited, P. Deslongchamps anomeric and gauche effects - some basic stereoelectronics, Anthony J. Kirby and Nicholas H. Williams anomeric effects - an iconoclastic view, Charles L. Perrin no kinetic anomeric effect in reactions of acetal derivatives, Michael L. Sinnott involvement of ns interactions in glycoside cleavage, C. Webster Andrews et al X-C-Z anomeric effect and Y-C-C-Z gauch effect (X,Y = O,S Z = O,N) - evaluation of the steric, electrostatic and orbital interaction components, B. Mario Pinto and Ronald Y.N. Leung origin and quantitative modeling of anomeric effect, Peter A. Petillo and Laura E. Lerner application of quantum theory of atoms in molecules to study of anomeric effect in dimethoxymethane, N.H. Westiuk et al anomeric and reverse anomeric effect in acetals and related functions, F. Grein glycosylmanganese complexes and anomeric anomalies - the next generation?, Philip DeShong et al do stereoelectronic effects control the structure and reactivity of trigonal- bipyramidal phosphoesters?, Philip Tole and Carmay Lim steroelectronic effects in pentaoxysulfuranes - putative intermediates in sulfuryl-group transfer, Dale R. Cameron and Gregory R.J. Thatcher O-C-N anomeric effect in nucleosides - a major factor underlying the experimentally observed eastern barrier to pseudorotation, Ravi K. Jalluri.