Abstract
Rotational constants ( A 0, B 0, C 0), centrifugal distortion constants (δ j , δ jk ,δ k , δ j , δ k ) and the H, F nuclear spin-nuclear spin coupling constant D aa HF of the hydrogen-bonded complex (CH 2) 2S⋯HP were determined by analysis of 18 μ a and μ b transitions observed by pulsed-nozzle, Fourier-transform microwave spectroscopy. An angular geometry in which the HF subunit is almost perpendicular to the plane of the (CH 2) 2S molecule and in which the S⋯H-F hydrogen bond deviates from linearity by ≈ 17° was established by an interpretation of the spectroscopic constants.
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