Abstract
An alternative approach to the derivation of the expressions for the function Z kl (to take account of effects beyond the vibrational and rotational motions of the nuclei) in the term coefficients of diatomic molecules is outlined. Application of the resulting expressions is made to the spinrotational coupling parameter of 12C 14N in the X 2Σ state and to the electric quadrupolar coupling parameter of the 35C l nucleus in H 35C l.
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