Abstract
ABSTRACTThe aggregation structure of lignin in aqueous solution had an important effect on the dispersion of lignin and the properties of lignin/styrene–butadiene rubber (SBR) composites. This article revealed the relationship between aggregation structure and chemical structure of modified lignin. Unmodified lignin was amorphous; however, our results showed that aldehyde‐modified lignin was transformed into spherical aggregates, while propylene‐oxide‐modified lignin self‐aggregated into supramolecular domains. The relationships between aggregation structure, filler dispersion, filler–rubber interaction, and performance were also studied by investigating the microstructure, viscoelastic behavior, and mechanical properties of lignin/SBR composites. Meanwhile, a solution to improve the coprecipitation efficiency of lignin and SBR latex was proposed. In this article, epoxidized natural rubber (ENR) was also used as compatibilizer to improve the interfacial adhesion between polar lignin and nonpolar SBR. The results showed better lignin dispersion for the ENR‐containing rubber composites, as well as superior wet skid resistance and lower rolling resistance. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 45759.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
