Abstract

The adsorption and corrosion inhibition of the anion surfactants such as Dodecyl Sulphonic Acid Sodium Salt (DSASS), Dodecyl Benzene Sulfonic Acid Sodium Salt (DBSASS) and Sodium Dodecyl Sulfate (SDS) on the aluminium surface in hydrochloric acid solution was studied using the weight loss method. It was found that the adsorption of surfactants could prevent aluminum from weight loss and the adsorption accorded with Langmuir equation. The thermodynamic parameters such as adsorption heat, adsorption entropy and adsorption free energy were calculated and the changes of the contact angles of aluminum sheets with and without surfactants were determined. According to the above mentioned experimental results, the relations between the adsorption and corrosion inhibition of the anion surfactants on aluminium surface were discussed.

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