Abstract

Abstract The absorption spectra of azobenzene and its para hydroxy, amino or dimethylamino derivative, and their sodium salts have been determined above 220 mμ in mixed solutions of water and ethanol (7 : 3 in volume) at various acidities. All the samples show characteristic changes in spectra with increase in the acidity, and the respective spectral changes keep well-defined isosbestic points, indicating a binary system spectrally. The wavelengths of the color band peaks and the corresponding spectral species have been determined. Consequently, the following order of the substitution effect has been obtained; (Remark: Graphics omitted.)

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