The 3d 2 D 5/2−2 D 3/2 magnetic dipole transition in potassium-like ions

Abstract

Spectral lines of the magnetic-dipole transition between the 3d2D3/2,5/2 levels of K-like Kr17+, Zr21+, Nb22+, Mo23+, and Ru25+ ions were measured in a compact electron beam ion trap. By means of dedicated calibration methods, the transition wavelengths of Kr17+, Zr21+, and Mo23+ ions reduce uncertainties by at least one order of magnitude and the wavelengths of Nb22+ and Ru25+ ions are measured for the first time at a few ppm level. In addition, the fine-structure energy splittings were systematically calculated using the multiconfiguration Dirac–Hartree–Fock method combined with the relativistic configuration interaction approach. The contributions of the core-valence and core-core electron correlations, the Breit interaction and QED effect were discussed in detail. The results show that it is essential to include deep core-valence correlation of L-shell and core-core valence correlation of 3p subshell to obtain an agreement better than 0.15% with existing experimental values. The calculation model can be performed to predict the wavelength within a high accuracy for a wide range of potassium-like ions.