Abstract
The crystal structure of 2:1 picric acid (PAH) with tetramethylpyrazine (TMP) was determined by using X-ray diffraction studies. Two equivalent +N H⋯O − hydrogen bonds are formed with the length of 2.601 Å (calculated 2.640 Å). In the IR spectra very broad doublet at ca. 2000 and 2400 cm −1 is observed, which can be interpreted as due to symmetric and asymmetric +N H vibrations. In neutron backscattering two tunnel splittings are observed, in agreement with the symmetry of 2:1 assemblies. At 4 K the tunnel peaks are located at 3.17 and 4.24 μeV.
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