Abstract
The neutral derivatives R 2Sn(dib) (R = Me, n-Bu, Ph and Cl; dib = quinquedentate dianion from diacetylpyridine bis(benzoyl)hydrazone) have been synthesized, and characterized by IR and multinuclear magnetic resonance spectroscopy. The complexes exhibit high-field δ( 119Sn) values owing to the pentagonal bipyramidal environment produced by the planar quinquedentate ligand. In Me 2Sn(dib) the absolute values of 1 J( 13C, 119Sn), 1215.0 Hz, and 2 J( 1H, 119Sn), 115.8 Hz are among the highest reported for diorganotin(IV) derivatives.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
