The 0-2 Transition of CO in Condensed Oxygen, Nitrogen, and Argon.

Abstract

Infrared absorption spectra of CO in the region of the first overtone have been observed in dilute (approximately 1 to 10 parts in 1000) liquid solutions of oxygen, nitrogen, and argon, and clear crystalline nitrogen and argon matrices. The overtone band was found at 4249.0, 4252.4, and 4252.0 cm−1 with half widths of 18.4, 17.8, and 13.7 cm−1 in liquid oxygen, nitrogen, and argon solutions at 82, 78, and 82 °K, respectively. The half width in liquid oxygen varied from 18.4 to 10.0 cm−1 in the temperature range 82 to 57 °K. The band position was the same but its width was smaller in the crystalline nitrogen matrix. Two bands were observed in the clear crystalline argon solid at 4245 and 4256 cm−1. The solution results cannot be interpreted with the recent theory of Buckingham.