Abstract
Recent kinetic and thermochemical data is analysed to set limits on the π bond energy, D π, in methylenedimethylsilane of 119 kJ/mol < D π < 192 kJ/mol. A rather more approximate limit of < 158 kJ/mol may be set for the π-bond energy in methylmethylenesilane. These figures indicate that the π-bond between Si and C is about half as strong as that in olefins.
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