Th-228/Th-232 and Pb-210 geochronologies in marine and lake sediments

Abstract

Two dating techniques, applicable to coastal marine and lacustrine sediments over periods ranging from years to a century, evolve from the natural radioactive series: Th-228/ Th-232 from the Th-232 series and Pb-210 from the U-238 series. There is an excess of Th-228 over and above that supported by the parents Th-232 or Ra-228 in such deposits. The amounts of Th-232-supported and Ra-228-supported Th-228 are similar, indicating that both radium and thorium isotopes are removed from solution in these coastal zones quite rapidly after introduction or formation. The radium isotopes are probably transferred from the overlying waters to the sediments via phytoplankton, where they are reportedly enriched. In the surface levels of the deposits analyzed, there is nearly an order of magnitude more unsupported than supported Th-228. This excess Th-228 can be used both for dating purposes over time periods of the order of a decade and as permissive evidence that the uppermost levels of the deposit were obtained during the coring operation. Preliminary results from several lakes indicate the possibility that Th-228/Th-232 geochronologies are held by their sediments. Average rates of accumulation of lake sediments have been obtained from decreases in Pb-210 activity as a function of depth, although surface layers of the deposits may not have been recovered in the coring operation. Finally, Pb-210 geochronologies have been extended from varved to unvarved marine sediments.