Abstract

We have observed nano-scale chemical composition separation in the thin film of La0.8Sr0.2MnO3 by means of high-angle-angular-dark-field imaging, elemental mapping, and composition line-scanning in a transmission electron microscope. It is found that highly dense and dimensionally uniform nano-agglomerates are embedded in the film. The ratio of Mn∕La in the nano-agglomerates is fluctuated and generally much higher than that in their surrounding medium. Such compositional inhomogeneities result in a textured microstructure, which is one of the most important parameters for tunning electronic properties in the colossal magnetoresistance oxides.

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