Abstract

In the anion of the title compound, (C24H20P)[Fe3(C7H7Te)(CO)12], each Fe0 atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal–bipyramidal coordination environment. The Te atom is coordinated by a 4-methyl­phenyl group and the Fe0 atoms in a distorted tetra­hedral geometry. The average Te—Fe bond length is 2.574 (4) Å.

Highlights

  • In the anion of the title compound, (C24H20P)[Fe3(C7H7Te)(CO)12], each Fe0 atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal–bipyramidal coordination environment

  • The Te atom is coordinated by a 4-methylphenyl group and the Fe0 atoms in a distorted tetrahedral geometry

  • Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

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Summary

Data collection

Sichuan University of Science & Engineering, Zigong, Sichuan 643000, People’s Republic of China. The average Te—Fe bond length is 2.574 (4) Å

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The authors are grateful to Sichuan Science and Technology
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