Abstract
The title compound, (C24H20P)[Re(C11H11N3O2S)O], is the [(C6H5)4P]+ salt of a square-pyramidal [ReOL]− complex anion [L is the deprotonated 2-(mercaptomethylcarbonylamino)-N-(2-methylaminophenyl)ethanamide ligand], in which the Re=O bond is apical and the tetradentate (N—N—N—S)4− ligand fills the four basal sites. The presence of a methyl group on the terminal N-atom donor induces a small displacement of the coordinated S atom.
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