Abstract
The reactions of pentaarylantimony with antimony derivatives Ar3SbX2(Ar = Ph or p-Tol and X = OC(O)C6F5or NO3) afford tetraphenylantimony pentafluorobenzoate (Ph4SbOC(O)C6F5) and tetra-p-tolylantimony nitrate (p-Tol4SbONO2). The compounds obtained were structurally characterized by X-ray diffraction analysis. The Sb atom in Ph4SbOC(O)C6F5has a distorted trigonal-bipyramidal environment with an axial perfluorobenzoate group. The trigonal-bipyramidal coordination of antimony in p-Tol4SbONO2is strongly distorted, with the O atom of the nitrato group lying in the axial plane.
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