Abstract
AbstractA tetranuclear manganese complex of the composition {Mn4[(Py)C(Ph)NO]4(CH3CH2OH)3(CH3CH2O)Cl3}·2H2O (1) was synthesized by solvothermal reaction, and characterized by X‐ray single crystal diffraction, IR spectroscopy, and elemental analysis. X‐ray analysis revealed that complex 1 contains a [Mn4(NO)4]4+ core with three MnII atoms displaying distorted octahedral arrangements and one MnII ion exhibiting a trigonal bipyramidal arrangement. Low‐temperature magnetic susceptibility measurement for the solid sample of 1 revealed antiferromagnetic MnII···MnII interactions.
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