Abstract
In the centrosymmetric binuclear title complex, [Pr2(C9H9O3)6(C12H8N2)2], the two PrIII ions are linked by four 2-phenoxypropionate (L) groups through their bi- and tridentate bridging modes. Each PrIII ion is nine-coordinated by one 1,10-phenanthroline molecule, one bidentate carboxylate group and four bridging carboxylate groups in a distorted PrN2O7 monocapped square-antiprismatic geometry. The title compound is isotypic with its terbium- and dysprosium-containing analogues.
Highlights
[Pr2(C9H9O3)6(C12H8N2)2], the two PrIII ions are linked by four 2-phenoxypropionate (L) groups through their bi- and tridentate bridging modes
Each PrIII ion is nine-coordinated by one 1,10-phenanthroline molecule, one bidentate carboxylate group and four bridging carboxylate groups in a distorted
As part of our ongoing studies of 2-phenoxypropionic acid complexes (Shen et al, 2011a,b) we describe the title
Summary
The title compound is isotypic with its terbium- and dysprosiumcontaining analogues
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