Abstract
In the centrosymmetric dinuclear title complex, [Sm2(C10H11O4)6(C12H8N2)2], the SmIII ion is nine-coordinated by seven O atoms of five 2-(3,4-dimethoxyphenyl)acetate (DMPA) ligands and two N atoms of one bis-chelating 1,10-phenanthroline (phen) ligand, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in bis-chelate, bridging and bridging tridentate modes. An intramolecular C—H⋯O hydrogen bond occurs. Intermolecular C—H⋯O interactions are also present in the crystal.
Highlights
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, People’s Republic of China, and, Zhejiang Normal University Xingzhi College, Jinhua 321004, People’s Republic of China
In the centrosymmetric dinuclear title complex, [Sm2(C10H11O4)6(C12H8N2)2], the SmIII ion is nine-coordinated by seven O atoms of five 2-(3,4-dimethoxyphenyl)acetate (DMPA) ligands and two N atoms of one bis-chelating 1,10phenanthroline ligand, forming a distorted tricapped trigonal-prismatic environment
The DMPA ligands coordinate in bis-chelate, bridging and bridging tridentate modes
Summary
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, People’s Republic of China, and, Zhejiang Normal University Xingzhi College, Jinhua 321004, People’s Republic of China
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