Abstract
In the title complex, [Cu(NO3)2(C10H8N2S)4], the CuII atom (site symmetry ) is coordinated by two monodentate nitrate ions and two monodentate di-4-pyridylsulfane ligands, resulting in a slightly distorted trans-arranged CuO2N4 octahedral geometry. Intramolecular C—H⋯O hydrogen bonds are present. In the crystal, adjacent molecules are linked via C—H⋯N hydrogen bonds into chains parallel to the a axis. Intermolecular C—H⋯O interactions also occur.
Highlights
In the title complex, [Cu(NO3)2(C10H8N2S)4], the CuII atom is coordinated by two monodentate nitrate ions and two monodentate di-4-pyridylsulfane ligands, resulting in a slightly distorted trans-arranged CuO2N4 octahedral geometry
The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry
The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2
Summary
R factor = 0.044; wR factor = 0.100; data-to-parameter ratio = 13.3. In the title complex, [Cu(NO3)2(C10H8N2S)4], the CuII atom (site symmetry 1) is coordinated by two monodentate nitrate ions and two monodentate di-4-pyridylsulfane ligands, resulting in a slightly distorted trans-arranged CuO2N4 octahedral geometry. Intramolecular C—H O hydrogen bonds are present. In the crystal, adjacent molecules are linked via C—H N hydrogen bonds into chains parallel to the a axis. Intermolecular C—H O interactions also occur.
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
