Abstract
The structure of the title compound, tetrakis(2-amino-1,5-dihydro-1-methyl-4H-imidazol-4-one-N 3 )platinum(II) dithiocyanate, [Pt(C 4 H 7 N 3 O) 4 ](SCN) 2 , consists of [Pt(creat) 4 ] 2+ (creat is 2-imino-1-methyl-4-imidazolidinone) complex cations possessing approximate D 2 symmetry and thiocyanate anions. The Pt atom is coordinated in a square-planar manner by four creatinine ligands bonded through their endocyclic N atoms. The Pt-N bond distances range from 1.980(6) to 2.034(7)A. The creatinine molecules are planar and participate in inter- and intramolecular hydrogen bonds. The ligands are almost perpendicular to the equatorial PtN 4 plane.
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Schedule a callMore From: Acta crystallographica. Section C, Crystal structure communications
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