Abstract
In the centrosymmetric binuclear title complex, [Ce2(C9H9O3)6(C12H8N2)2], the two CeIII ions are linked by four 2-phenoxypropionate groups in bi- and tridentate bridging modes. Each CeIII ion is nine-coordinated by one 1,10-phenanthroline molecule, two O atoms from a chelating carboxylate, two O atoms derived from a μ3-carboxylate and two O atoms derived from two μ2-carboxylate ligands in a distorted CeN2O7 monocapped square-antiprismatic geometry.
Highlights
[Ce2(C9H9O3)6(C12H8N2)2], the two CeIII ions are linked by four 2-phenoxypropionate groups in bi- and tridentate bridging modes
1,10-phenanthroline molecule, two O atoms from a chelating carboxylate, two O atoms derived from a 3-carboxylate and two O atoms derived from two 2-carboxylate ligands in a monocapped square-antiprismatic distorted
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
Tetrakis(l2-2-phenoxypropionato)j3O,O0 :O0 ;j3O:O,O0 ;j4O:O0 -bis[(1,10phenanthroline-j2N,N0 )(2-phenoxypropionato-j2O,O0 )cerium(III)]. College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People’s Republic of China, and bZhejiang Normal University Xingzhi. R factor = 0.032; wR factor = 0.060; data-to-parameter ratio = 13.8
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