Abstract
The structure of the title compound, [Mn(NCS)2(C6H8N2)4], consists of isolated molecules of [Mn(NCS)2(Aim)4] (Aim = 1-allylimidazole), which contain a compressed octahedral MnN6 chromophore (site symmetry ). The NCS− anions are trans and four N atoms from the Aim ligands define the equatorial plane. The mean Mn—N(Aim) and Mn—N(NCS) distances are 2.270 and 2.229 Å, respectively. Weak C—H⋯N interactions contribute to the crystal packing stability.
Highlights
Data collectionJuan Zhaoa* and Yan-Ling Jinb a College of Mechanical Engineering, Qingdao Technological University, Qingdao
The structure of the title compound, [Mn(NCS)2(C6H8N2)4], consists of isolated molecules of [Mn(NCS)2(Aim)4] (Aim = 1allylimidazole), which contain a compressed octahedral MnN6 chromophore
Weak C—H N interactions contribute to the crystal packing stability
Summary
Juan Zhaoa* and Yan-Ling Jinb a College of Mechanical Engineering, Qingdao Technological University, Qingdao. 266033, People’s Republic of China, and bKey Laboratory of Advanced Materials, Qingdao University of Science and Technology, Qingdao 266042, People’s Republic of China. R factor = 0.059; wR factor = 0.162; data-to-parameter ratio = 15.8. The structure of the title compound, [Mn(NCS)2(C6H8N2)4], consists of isolated molecules of [Mn(NCS)2(Aim)4] (Aim = 1allylimidazole), which contain a compressed octahedral MnN6 chromophore (site symmetry 1). The NCS anions are trans and four N atoms from the Aim ligands define the equatorial plane. The mean Mn—N(Aim) and Mn—N(NCS) distances are 2.270 and 2.229 Å, respectively. Weak C—H N interactions contribute to the crystal packing stability
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