Abstract

U(BH4)3(THF)x, (THF = tetrahydrofuran,) and (η5-C5H5)UCl3 react with 2-(diphenylphosphino)pyridine, (Ph2Ppy), producing 1:2 and 1:1 adducts, respectively; and X-ray crystal structure of U(BH4)3(Ph2Ppy)2·1/2C6H6 shows U–P = 3.162(1) and U–N = 2.659(4)A.

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