Abstract
In this paper, the first investigation of stimulated Raman scattering (SRS) effects in the tetragonal crystal LiLuF4 is presented. It is known as a promising host-material for trivalent lasant lanthanides (Ln3+). We discovered its three “original” and one “combined” SRS-promoting modes at room temperature under picosecond laser excitation in the visible and near-IR spectral range. Apart from multi-phonon Stokes and anti-Stokes generation, we observed cross-cascaded χ(3) ↔ χ(3) processes involving different pairs of SRS-active phonons. Furthermore, a comparative estimation of the stead-state Raman gain coefficient for first Stokes generation in LiLuF4 related to the most active SRS-phonon mode with ωSRS1 ≈ 323 cm−1 has been carried out for both the visible and near-IR. A brief review of the pioneering publications on laser action in Ln3+-ions of all known fluoride SRS-active single crystals is given in tabular form as well.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
