Abstract

In the title compound, [Co(C6H6N2O)2(H2O)4](C8H4O4)·2H2O, the CoII atom (site symmetry \overline{1}) exhibits a slightly distorted trans-CoN2O4 octa­hedral coordination geometry arising from two N-bonded isonicotinamide mol­ecules and four O atoms of water mol­ecules. The uncoordinated centrosymmetric terephthalate anion and uncoordinated water mol­ecules inter­act with the cation by way of O—H⋯O and N—H⋯O hydrogen bonds, generating a three-dimensional network.

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