Abstract
In the title complex, [Cu(C9H6N3O3S)2(H2O)4]·2H2O, the CuII atom lies on an inversion centre and is coordinated by four water molecules in equatorial positions and two N atoms from two 4-(4-pyridyl)pyrimidine-2-sulfonate ligands in apical positions. The asymmetric unit contains half of the complex and one free water molecule. The water molecules, including the uncoordinated water molecules, and sulfonate O atoms are involved in O—H⋯O and O—H⋯N hydrogen-bonding interactions.
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