Abstract

The asymmetric unit of the title compound, [Zn(C3H7NO)2(H2O)4][Zn(C13H10N2O5)Cl]2, is composed of a single anion and half a cation. The ZnII atom in the monoanion has a distorted triganol–pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(carboxyl­ato­meth­oxy)phen­yl]pyrazol-1-yl}acetate ligand and one Cl atom. In the dication, the ZnII atom is located on an inversion center and is coordinated by six O atoms in a slightly distorted octa­hedral geometry. In the crystal, the ions are linked by O—H⋯O hydrogen bonds, forming a two-dimensional network lying parallel to the ab plane. There are also C—H⋯O and C—H⋯Cl inter­actions present, which lead to the formation of a three-dimensional structure.

Highlights

  • The asymmetric unit of the title compound, [Zn(C3H7NO)2(H2O)4][Zn(C13H10N2O5)Cl]2, is composed of a single anion and half a cation

  • The ZnII atom is located on an inversion center and is coordinated by six O atoms in a slightly distorted octahedral geometry

  • The ions are linked by O—

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Summary

Rigaku Mercury diffractometer

R factor = 0.053; wR factor = 0.168; data-to-parameter ratio = 17.8. The asymmetric unit of the title compound, [Zn(C3H7NO)2(H2O)4][Zn(C13H10N2O5)Cl]2, is composed of a single anion and half a cation. The ZnII atom in the monoanion has a distorted triganol–pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(carboxylatomethoxy)phenyl]pyrazol-1-yl}acetate ligand and one Cl atom. The ZnII atom is located on an inversion center and is coordinated by six O atoms in a slightly distorted octahedral geometry. H O hydrogen bonds, forming a two-dimensional network lying parallel to the ab plane. C—H Cl interactions present, which lead to the formation of a three-dimensional structure

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This work was supported by the Foundation of Suzhou
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