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Abstract
The covalently bonded monodentate carboxylate groups in the title compound, [Ni(C7H5O4)2(H2O)4]·3H2O, are trans to each other; the octahedrally coordinated Ni atom lies on a pseudo-center of inversion that relates the carboxylate groups to each other as well as two coordinated water molecules to the other two. Extensive hydrogen bonding leads to the formation of a three-dimensional network.
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