Abstract

In the title compound, [Co(C9H6N3O3S)2(H2O)4]·H2O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetate ligands are monodentate. One coordinates the metal atom via the pyridyl N atom whereas the other coordinates via the carboxyl­ate O atom. The CoII atom adopts a slightly distorted octa­hedral coordination geometry with four O atoms of the coordinated water mol­ecules located in the equatorial plane and the N and O atoms of the two POA ligands in axial positions. In the crystal, the components are connected through O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional framework.

Highlights

  • In the title compound, [Co(C9H6N3O3S)2(H2O)4]ÁH2O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate ligands are monodentate

  • The CoII atom adopts a slightly distorted octahedral coordination geometry with four O atoms of the coordinated water molecules located in the equatorial plane and the N and O atoms of the two POA ligands in axial positions

  • For zinc and cadmium metal-organic polymers formed with 5-(4-pyridyl)-1,3,4oxadiazole-2-thiol, see: Du et al (2006)

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Summary

Structure Reports Online

Tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4oxadiazol-2-yl]sulfanyl}acetato)cobalt(II) monohydrate Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.007 A; R factor = 0.065; wR factor = 0.182; data-to-parameter ratio = 11.4. Crystal data [Co(C9H6N3O3S)2(H2O)4]ÁH2O Mr = 621.47 Triclinic, P1 a = 7.393 (4) Ab = 11.122 (6) Ac = 16.014 (8) A = 103.904 (6) = 96.040 (6)

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