Abstract
The title compound, [Mg(C10H8N2)(H2O)4](C7H4FO2)2, consists of a bivalent [Mg(C10H8N2)(H2O)4]2+ cation and two 4-fluorbenzoate anions. In the complex cation, the MgII atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and four water O atoms in a distorted MgN2O4 octahedral geometry. The MgII atom is located on a twofold rotation axis and thus a cation exhibits C 2 molecular symmetry. The 2,2′-bipyridine ligands exhibit nearly perfect planarity (r.m.s. deviations = 0.0061 Å). In the crystal, O—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional supramolecular network.
Highlights
The title compound, [Mg(C10H8N2)(H2O)4](C7H4FO2)2, consists of a bivalent [Mg(C10H8N2)(H2O)4]2+ cation and two 4-fluorbenzoate anions
The MgII atom is located on a twofold rotation axis and a cation exhibits C2 molecular symmetry
Symmetry codes: (ii) −x+1/2, y+1/2, z; (iii) −x+1/2, −y+1/2, z−1/2; (iv) x−1/2, −y+1/2, −z; (v) −x+1/2, y−1/2, z
Summary
Bi-Song Zhang,a* Jian-Ping Qiu,a Li-Hua Liua and Wei Xub a College of Material Science and Chemical Engineering, Jinhua College of Profession and Technology, Jinhua, Zhejiang 321017, People’s Republic of China, and b.
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