Abstract
The simplest unit of the title compound, [Zn 2 (C 15 H 14 N 2 O 8 )(H 2 O) 4 ].2H 2 O, is a dinuclear Zn II complex bridged by the O atoms of one carboxylate moiety of the 3,4-toluenediamine-N,N,N',N'-tetraacetate ligand (3,4-tdta). The coordination geometry of the zinc-3,4-tdta moiety is close to trigonal prismatic, whereas the other zinc ion is in a nearly O h environment comprising two O atoms from carboxylate groups of different ligands and four water molecules. The other two water molecules are waters of crystallization in the polynuclear complex [Zn-μ-(3,4-tdta)-Zn(H 2 O) 4 ] n .2H 2 O n .
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