Abstract
The reaction of [Mo2(SC6H11)2(CO)8] and (C4H9)4NBr in acetone affords a new dinuclear molybdenum(I) complex, [(C4H9)4N][Mo2Br(C6H11S)2(CO)6]. The crystal structure revealed the MoS2Mo core to be planar; the Br atom coordinates to two Mo atoms, forming another bridge.
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