Abstract
The title complex, [Pt4Br4(CH3)12], the tetramer of trimethylplatinum(IV) bromide, reveals a distorted cubane-like structure and is disposed about a crystallographic mirror plane passing through two Pt atoms, two Br atoms and two methyl groups parallel to the ac plane. The tetrameric complex displays pseudo-cubic molecular symmetry, \overline{4}3m. The coordination geometry around each Pt centre is distorted octahedral. The tetrameric units in the crystal structure are packed by hydrophobic interactions or van der Waals contacts.
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