Abstract
The title compound, [Cu2(CH3CO2)4(C7H5NS)2] or [(C7H5NS)Cu]2(μ-O2CCH3)4, crystallizes with one molecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond. The acetate ligands form slightly distorted square planes around each metal ion, while the copper ions are displaced by 0.2089 (4) Å from these planes towards the N atoms. Thus, the Cu—Cu distance is elongated to 2.6378 (7) Å, compared with the 2.2180 (7) Å distance between the two basal planes. The angle between the basal plane and the Cu—N bond is 4.84 (6)°.
Highlights
The title compound, [Cu2(CH3CO2)4(C7H5NS)2] or [(C7H5NS)Cu]2(-O2CCH3)4, crystallizes with one molecule per unit cell
Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HG5042)
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.005 A; R factor = 0.032; wR factor = 0.075; data-to-parameter ratio = 16.9. The title compound, [Cu2(CH3CO2)4(C7H5NS)2] or [(C7H5NS)Cu]2(-O2CCH3), crystallizes with one molecule per unit cell. Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond. The acetate ligands form slightly distorted square planes around each metal ion, while the copper ions are displaced by 0.2089 (4) Afrom these planes towards the N atoms. The Cu—Cu distance is elongated to 2.6378 (7) A , compared with the 2.2180 (7) Adistance between the two basal planes. The angle between the basal plane and the Cu—N bond is 4.84 (6)
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