Abstract
The crystal structure of the title compound, [Cu2(C2H3O2)4(C10H14N2O)2], reveals a dinuclear CuII complex located about a center of inversion. The coordination environment of each CuII cation is distorted octahedral, composed of four bridging acetate ligands, an apical pyridine donor and is completed by a Cu—Cu bond. The amide H atom forms intramolecular hydrogen bonds to two carboxyl O atoms. In the crystal, weak intermolecular pyridine–amide C—H⋯O interactions are also present.
Highlights
H atoms treated by a mixture of independent and constrained refinement max = 0.73 e Å3
The crystal structure of the title compound, [Cu2(C2H3O2)4(C10H14N2O)2], reveals a dinuclear CuII complex located about a center of inversion
Amide functionalized pyridine ligands have the potential to be used in the synthesis of supramolecular materials; transition metal coordination polymers
Summary
H atoms treated by a mixture of independent and constrained refinement max = 0.73 e Å3. R factor = 0.035; wR factor = 0.094; data-to-parameter ratio = 16.9. Symmetry code: (i) x þ 1; y þ 1; z þ 1. The crystal structure of the title compound, [Cu2(C2H3O2)4(C10H14N2O)2], reveals a dinuclear CuII complex located about a center of inversion. The coordination environment of each CuII cation is distorted octahedral, composed of four bridging acetate ligands, an apical pyridine donor and is completed by a Cu—Cu bond. The amide H atom forms intramolecular hydrogen bonds to two carboxyl O atoms. Weak intermolecular pyridine–amide C—H O interactions are present. Symmetry codes: (ii) x þ 2; y þ 1; z þ 2; (iii) x; y þ 32; z þ 12
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