Abstract
The Stokes-Einstein (SE) relation has been widely applied to quantitatively describe the Brownian motion. Notwithstanding, here we show that even for a simple fluid, the SE relation may fail over a wide range of the Brownian particle's size. Namely, although the SE relation could be a good approximation for a large enough Brownian particle, a significant error may appear when decreasing the Brownian particle's size down to several hundred times the size of the fluid molecules, and the error increases with the decrease of the Brownian particle's size. The cause is rooted in the fact that the kinetic contribution to the diffusion coefficient is inversely proportional to the squared radius of the Brownian particle. After excluding the kinetic contribution, we show that the applicable range of the SE relation is expanded significantly.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
