Ternary recombination of excited Ar+(P1/22) ions, established experimental results reinterpreted with a new extended model.

Abstract

For many years, the recombination of excited ions of argon, Ar+(P1/22), has been assumed negligible under ambient conditions as compared to the recombination of ground-state ions, Ar+(P3/22). This opinion was confronted with detailed experimental results that seem to clearly support it. Here, we propose a new interpretation in light of our recent calculations, which shows that the recombination efficiency is comparable for both fine-structure states. Noteworthily, in our model leading to a picture consistent with the experiment, residual dimer ions emerge from Ar+(P1/22) due to non-adiabatic dynamics effects and interplay in measured data.