Abstract
High pressure copolymerizations of ethene and 1-hexene were performed by use of a ternary catalyst system based on Me2Si[Ind]2ZrCl2, A1(iBU)3 and [PhNHMe2][B(C6F5)4]. The productivity depends strongly on the molar ratio of [Al]/[Zr] used. With small amounts of 1-hexene in the feed a rate enhancement of the ethene polymerization rate was observed. Incorporation of 1-hexene in the polymer was studied as well as the influence of 1-hexene on polymer density.
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