Abstract

The first ternary chromium(III)-histidine-nucleotide complexes with purine and pyrimidine bases are described in the solid state. A histidine molecule of the starting chromium(III)-histidine complex is always removed during the reaction with the nucleotide. The starting histidine complexes and the ternary histidine-nucleotide-chromium(III) complexes have been characterized by elemental analyses, conductivity measurements, infrared and electronic spectroscopy, and by EPR and thermogravimetric analyses for the CMP derivatives. These results can afford more insight into chromium biochemistry.

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