Abstract
Present chelate produces a typical terbium(III) emission spectrum during dissolution of X-ray irradiated sodium chloride in aqueous chelate solutions. The observed emission is predominantly chemiluminescence produced by the dissolution generated free radicals. The excitation of chelate proceeds dominatingly by a ligand oxidation-initiated route where the chemically excited ligand transfers energy intramolecularly to the central ion which is finally radiatively deexcitated.
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