Abstract

Compositionally complex alloys, or high entropy alloys, are good candidates for applications at higher temperatures in gas turbines. After their introduction, the equiatomic Al17Co17Cr17Cu17Fe17Ni17 (at.%) served as a starting material and a long optimization road finally led to the recently optimized Al10Co25Cr8Fe15Ni36Ti6 (at.%) alloy, which shows promising mechanical properties. Investigations of the as-cast state and after different heat treatments focus on the evolution of the microstructure and provide an overview of some mechanical properties. The dendritic solidification provides two phases in the dendritic cores and two different ones in the interdendritic regions. Three of the four phases remain after heat treatments. Homogenization and subsequent annealing produce a γ-γ’ based microstructure, similar to Ni-based superalloys. The γ phase is Co-Cr-Fe rich and the γ’ phase is Al-Ni-Ti rich. The understanding of the mechanical behavior of the investigated alloy is supported and enhanced by the study of the different phases and their nanohardness measurements. The observations are compared with mechanical and microstructural data from commercial Ni-based superalloys, Co-based alloys, and Co-Ni-based alloys at the desired application temperature of ~800 °C.

Highlights

  • IntroductionHigh entropy alloys (single phase) and compositionally complex (more phases, based on the high entropy effect) alloys have shown promising mechanical properties since the beginning of their discovery

  • High entropy alloys and compositionally complex alloys have shown promising mechanical properties since the beginning of their discovery

  • The homogenized samples were aged at 900 ◦ C or at 950 ◦ C for different times, i.e., 5 and 50 h (900 ◦ C) and 50, 100, 200, 500, and 100 h (950 ◦ C), and cooled down in the furnace to room temperature to prevent cracking at the grain boundaries

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Summary

Introduction

High entropy alloys (single phase) and compositionally complex (more phases, based on the high entropy effect) alloys have shown promising mechanical properties since the beginning of their discovery. Compositionally complex alloys (CCA) is focused on their use in industrial applications as a replacement for Ni-based or Co-based alloys. The latter commonly find their applications in aircraft turbines. There is a high demand for increasingly efficient materials, for aircraft turbines, and for the generation of USC (ultra-supercritical) power plants. In this case, the efficiency must be increased, which means that the materials need to withstand temperatures of up to 750 ◦ C [1].

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