Abstract

AbstractBlend films of polypropylene/poly(ethylene‐octane) at various mixing times are prepared by freezing‐microtome. The temporal evolution of their phase morphologies is investigated by phase contrast microscope (PCM). The digital image analysis, which contains the analysis in both real and wave‐number space, is introduced to deal with the PCM graphs. The characteristic length, L in real space, the average domain spacing, and the average chord lengths in wave‐number space, are used to express the domain sizes of two phases. The temporal evolution of phase morphology reaches the dynamic equilibrium between breakup and coalescences of domains at the late stage of mixing. In addition, two different fractal dimensions are defined to discuss the symmetry of the distribution of dispersed phase domains and the distribution uniformity: Df for the symmetry and Dc for the uniformity. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007

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