Abstract
Because of their molecular sieving properties, metal–organic frameworks have a high potential for application in gas storage, separation, and sensing. However, their real-world implementation will ...
Highlights
Metal-organic frameworks (MOFs) are microporous crystalline coordination polymers built from metal ion nodes connected by organic linkers.[1]
Since DMF decomposes to formic acid when heated in the presence of moisture, it can serve as a linker precursor in α-magnesium formate (α-MgFm) synthesis.[16]
The much higher volatility of DMF compared to 1,3-benzene-ditetrazole makes α-MgFm a promising candidate for metal-organic frameworks (MOFs)-chemical vapor deposition (CVD)
Summary
Metal-organic frameworks (MOFs) are microporous crystalline coordination polymers built from metal ion nodes connected by organic linkers.[1]. We report the solvent-free synthesis of the ultramicroporous α-magnesium formate (α-MgFm) based on the solid-vapor reaction of magnesium oxide (MgO) and formic acid, and establish the requirement for a structure-directing agent (SDA).
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