Templated Nanopores for Robust Functional Surface Porosity in Poly(methyl methacrylate)

Abstract

A novel "sink and etch" technique is used to generate stable surface nanoporosity in poly(methyl methacrylate). Layer-by-layer assembly is first used to conformally coat PMMA substrates with a uniform layer of silica nanoparticles. Thermal annealing is then applied to cause sinking and engulfment of the silica nanoparticles into the thermoplastic PMMA surface. By selectively etching away the layer of embedded silica nanoparticles, a conformal porous layer of inversely templated structure can be obtained in the PMMA surface. Characterization with atomic force microscopy shows that a variety of nanoporous surface morphologies can be achieved simply by controlling the duration and temperature of thermal annealing. The nanoporous surfaces consisting of either as assembled silica nanoparticles or templated inverse porosity in PMMA were compared in terms of their antireflective (AR) properties. Measuring AR properties provided a quantitative means to compare the stability of these porous AR surfaces before and after several cleaning cycles. Our results show that while both types of surface porosity can provide excellent AR properties (optimized for 300-400 nm), the porous layer generated by the "sink and etch" technique showed superior mechanical stability.