Template Syntheses and Crystal Structures of Nickel(II) Complexes of Hexaaza Macrocyclic Ligands with Pendant Functional Groups: Formation of a Coordination Polymer

Abstract

published in Advance ACS Abstracts, October 15, 1994. (1) Hay, R. W.; Pujari, M. P.; Thomas Moodie, W.; Craig, S.; Richens, D. T.; Perotti, A,; Ungaretti, L. J . Chem. Soc., Dalton Trans. 1987, 2605. (2) Barefield, E. K.; Foster, K. A,; Freeman, G. M.; Hodges, K. D. Inorg. Chem. 1986, 25, 4663. (3 ) Tschudin, D.; Basak, A,; Kaden, T. A. Helv. Chim. Acta 1988, 71, 100. (4) Freeman, G. M.; Barefield, E. K.; Van Derveer, D. G. Inorg. Chem. 1984, 23, 3092. ( 5 ) For reviews: (a) Kimura, E. Tetrahedron, 1992, 48, 6175. (b) Bemhardt, P. V.; Lawrance, G. A. Coord. Chem. Rev. 1990,104,297. (c) Kaden, T. A. Comments Inorg. Chem. 1990, IO, 25. (d) Kimura, E. Crown Ethers and Analogous Compounds; Kiraoka, M., Ed.; Elsevier: Amsterdam, 1992; p 381. (6) Lawrance, G. A,; Martinez, M.; Skelton, B. W.; White, A. H. J . Chem. Soc., Dalton Trans. 1992, 823. (7) Kimura, E.; Haruta, M.; Koike, T.; Shinoya, M.; Takenouchi, K.; Iitaka, Y. Inorg. Chem. 1993, 32, 2779. sized by inserting the metal ions in the free ligands which were prepared by rather elaborate many-step procedures. Recently, we have been interested in the macrocyclic complexes containing pendant donors which are capable of intraor intermolecular coordination and tried to synthesize them by the simple one pot template condensation reaction instead of a many-step procedure. Over the last few years, various saturated polyaza multidentate, macrocyclic, and macropolycyclic complexes have been prepared by the template condensation reactions involving formaldehyde and Especially, we have developed a simple procedure for the preparation of the complexes of hexaaza macrocyclic ligand which resembles 1,4,8,11tetraazacyclotetradecane (cyclam). By modifying a previous method, we have synthesized the complexes of macrocyclic (8) Suh, M. P.; Shin, W.; Kim, D.; Kim, S. Inorg. Chem. 1984,23, 618. (9) Suh, M. P.; Kim, D. Inorg. Chem. 1985, 24, 3712. (10) Suh, M. P.; Shin, W.; Kim, H.; Koo, C. H. Inorg. Chem. 1987, 26, (11) Suh, M. P.; Kang, S. Inorg. Chem. 1988, 27, 2544. (12) Jung, S.; Kang, S.; Suh, M. P. Bull. Kor. Chem. SOC. 1989, 10, 362. (13) Suh, M. P.; Shin, W.; Kang, S.-G.; Lah, M. S.; Chung, T. M. Inorg. Chem. 1989, 28, 1602. (14) Suh, M. P.; Kang, S. V. Goedken, Park, S. Inorg. Chem. 1991, 30, 365. (15) Bernhardt, P. V.; Curtis, L. S.; Curtis, N. F.; Lawrance, G. A,; Skelton, B. W.; White, A. H. Aust. J . Chem. 1989, 42, 797. (16) Fabbrizzi, L.; Lanfredi, A. M. M.; Pallavicini, P.; Perotti, A,; Taglitti, A.; Ugozzoli, F. J . Chem. Soc., Dalton Trans. 1991, 3263. (17) Blas, A. D.; Santis, G. D.; Fabbrizzi, L.; Liccelli, M.; Lanfredi, A. M. M.; Pallacicini, P.; Poggi, A.; Ugozzoli, F. Inorg. Chem. 1993, 106. 1846. 0020166919411333-5509$04.50/0