Temperature-dependent magnetic anisotropy from pseudo-dipolar interactions

Abstract

Magnetic anisotropy of spin models with directional-dependent interactions in the high-temperature paramagnetic phase is theoretically studied. Using a high temperature expansion, we show that the Ising type directional-dependent interaction gives rise to magnetic anisotropy which depends on the temperature as $\propto T^{-5}$. This phenomenon arises from the anisotropic exchange interaction, and is distinct from the orbital effect, such as van Vleck susceptibility. It is shown that while the quadratic term in the magnetization favors to point the spins along the bond, the fourth order term in magnetization prefers to point spins to the perpendicular direction. The theory is applied to the Heisenberg-Kitaev model on the honeycomb lattice and a cubic lattice model that is potentially relevant to perovskite iridates. We show that, in these models, the anisotropic terms in quadratic order cancels out, and the leading order for the magnetic anisotropy arises from the fourth order contribution. The result shows that the anisotropy from the directional-dependent interaction gives rise to $\langle100\rangle$ magnetic anisotropy. These results are potentially relevant to heavy transition metal oxides such as iridates. Experimental observation of the magnitude of anisotropic interactions using magnetic torque measurement is also discussed.