Temperature-dependent luminescence of Bi3+, Eu3+ co-activated La2MgGeO6 phosphor for dual-mode optical thermometry

Abstract

Using a high-temperature solid-phase method, a series of La2MgGeO6: Bi3+, Eu3+ samples with different doping amounts of Bi3+ and Eu3+ were obtained. The crystal structure, morphology, luminescence characteristics, temperature-varying luminescence spectrum, fluorescence attenuation curve, and energy transfer mechanism of the samples were explored. In La2MgGeO6: Bi3+, Eu3+ phosphors, Bi3+ and Eu3+ ions occupy the La3+ ion position. Under ultraviolet (UV) excitation, the emission spectra of LMGO: Bi3+ and the excitation spectra of LMGO: Eu3+ have significant spectral overlap, indicating that there is energy transfer between Bi3+ and Eu3+. By adjusting the doping amounts of Eu3+, adjustable luminescence can be obtained in the co-doped samples. According to the varying temperature-dependence trends of Bi3+ and Eu3+ ions, fluorescence intensity ratio technology was used to explore the temperature-sensing characteristics of Bi3+ and Eu3+ ions. The maximum absolute sensitivity and relative sensitivity were 0.074%·K−1 and 2.389%·K−1, respectively. In addition, by monitoring the lifetime decay time of Bi3+ with temperature, the maximum temperature sensitivity of the La2MgGeO6: Bi3+ samples was 4.09%·K−1. The above results indicate that La2MgGeO6: Bi3+, Eu3+ samples can be used as potential luminescent materials for temperature detection.