Temperature-associated changes in groundwater quality

Abstract

Climate change and urbanization are currently leading to a warming of the subsurface worldwide with yet unforeseen consequences for groundwater quality. The temperature-sensitivity of chemical and biological processes suggests that small temperature changes driven by current warming should have a detectable effect on the ecology of aquifers and the composition of groundwater itself, but field observations covering temperatures that are environmentally relevant are sparse. The analysis of a large data set provides field-scale evidence that, within the naturally occurring temperature range between 5 and 20 °C, temperature affects the quality of groundwater. A difference in temperature of +1 K is linked to a 4% decline in oxygen saturation and a pH drop of 0.02 due to the accumulation of carbon dioxide. Further, warmer groundwater shows signs of enhanced mineral weathering and higher concentrations of drinking water-relevant elements such as manganese. The observed trends in groundwater quality are consistent with a temperature-associated intensification of microbial metabolic rates and enhanced organic matter mineralization at warmer temperatures either within the aquifers or in the overlying soils. A times series analysis reveals that soil and groundwater temperatures in the studied area have been increasing at a rate of 0.1–0.4 K per decade -comparable to recent global warming- driving subtle, but distinct changes in groundwater pH and oxygen concentrations. The results confirm, that certain but central aspects of groundwater quality (pH, O2, pCO2, Mn, DOC) change due to warming, which may increase the costs for purification when drinking water is produced from groundwater resources and may turn some aquifers uninhabitable for groundwater biota.